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A New Non-Centrosymmetricorganotin (IV) Hybrid Compound C5H14N2 [SnCl6] 2H2O: Crystal Structure And Optical Study Characterization

Article scientifique 2021 Anglais

Résumé

Abstract A new non-centrosymmetricorganotin (IV) hybrid compoundC5H14N2 [SnCl6] 2H2O was determined by single crystal X-ray diffraction at 150(2) K. Its crystal structure was solved by single crystal X-ray diffraction reveling that compound crystallizes in the orthorhombic system with Pbca space group with the following lattice parameters: a = 12.1486 (15) Å, b= 15.4571 (17) Å, c = 16.7610 (18) Å with Z = 8. The bonding between inorganic and organic entities in the compounds is realized by hydrogen bonding O−H…O ,O−H…Cl , NH • • • Cl, N-H…Cl and O−H…Cl. Finally,UV-visible absorption measurements exhibit two absorption bands (226 nm and 262 nm).The optical band gap (Eg) is deduced to be 3.46 Ev.

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Hannachi, N., Roisnel, T., Hlel, F. (2021). A New Non-Centrosymmetricorganotin (IV) Hybrid Compound C5H14N2 [SnCl6] 2H2O: Crystal Structure And Optical Study Characterization. https://doi.org/10.21203/rs.3.rs-840421/v1

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Nejeh Hannachi Thierry Roisnel F. Hlel

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