Electrical and mechanical properties of (Bi,Pb)-2223 substituted by holmium

Résumé

The effect of the partial substitution of Ca2+ by Ho3+ ions on the electrical and mechanical properties of the superconducting phase (Bi,Pb)-2223 was studied. Superconducting samples of the type (Bi1.8Pb0.4)Sr2Ca2.1−x Ho x Cu3.1O10+δ were prepared by solid-state reaction technique under ambient pressure, and characterized by means of X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The superconducting transition temperature T c and pseudogap temperature T* were estimated from electrical resistivity measurements, while the critical current density J c was determined from I–V curves. The electrical resistivity data were discussed according to bipolaron model in the absence of thermally excited individual polarons. The sample with x = 0.025 showed the highest phase volume fraction, T c, and J c. Room temperature Vickers microhardness measurements were carried out at different applied loads (0.25–5 N) in order to investigate the performance of the mechanical properties of (Bi1.8Pb0.4)Sr2Ca2.1−x Ho x Cu3.1O10+δ phase. It was found that all the samples exhibit normal indentation size effect (ISE). The Vickers microhardness number H V increased as x increased from 0 to 0.025. The experimental results were discussed in view of Meyer’s law, Hays–Kendall (HK) approach, elastic/plastic deformation (EPD) model, and proportional specimen resistance (PSR) model. The load independent (true) microhardness of (Bi1.8Pb0.4)Sr2Ca2.1−x Ho x Cu3.1O10+δ superconducting samples showed identical behavior to that of the PSR model.

Citer ce document

Accès au document

Ce document est hébergé sur son dépôt institutionnel d'origine.

Auteur(s)

Statistiques

Consultations : 3

Téléchargements : 0